拓辉新材料醋酸乙烯 · 英文 MSDS
Safety Data Sheet
SECTION 1: Identification of the substance/mixture and of the company/undertaking
>Product identifier
- Product name: Vinyl acetate
- CBnumber: CB7852732
- CAS: 108-05-4
- EINECS Number: 203-545-4
- Synonyms: vinyl acetate,VAM
>Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
>Company Identification
- Company: Linyi Tuohui New Materials Co., Ltd.
- Address: Room A6159, 6F, Building 1, Linyi Software Park, No.6 Yihe Road, Zhimadun Subdistrict, Yishui New Area, Linyi City, Shandong Province, China
- Telephone: +86 176 6460 5089 (Manager Niu) / +86 130 4664 1786 (Manager Li)
- Email: nathan@tuohui-chem.com
- WhatsApp: +86 176 6460 5089
- Emergency telephone: +86 176 6460 5089
SECTION 2: Hazards identification
>GHS Label elements, including precautionary statements
- Symbol(GHS)
- Signal wordDanger
Precautionary statements
Hazard statements
SECTION 3: Composition/information on ingredients
>Substance
- Product name: Vinyl acetate
- Synonyms: vinyl acetate,VAM
- CAS: 108-05-4
- EC number: 203-545-4
- MF: C4H6O2
- MW: 86.09
SECTION 4: First aid measures
>Description of first aid measures
General advice
If inhaled
In case of skin contact
In case of eye contact
If swallowed
>Most important symptoms and effects, both acute and delayed
>Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
>Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing media
>Special hazards arising from the substance or mixture
Carbon oxides
Flash back possible over considerable distance., Container explosion may occur under fire conditions.
>Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
>Further information
Use water spray to cool unopened containers.
>NFPA 704
SECTION 6: Accidental release measures
>Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
>Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
>Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).
>Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
>Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
For precautions see section 2.2.
>Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
Recommended storage temperature 2 - 8 °C
>Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
>control parameter
Hazard composition and occupational exposure limits
>Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Splash contact Material: butyl-rubber
Minimum layer thickness: 0,3 mm Break through time: 232 min
Material tested:Butoject (KCL 897 / Aldrich Z677647, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Where risk assessment shows air-purifying respirators are appropriate use a full- face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Exposure limits
SECTION 9: Physical and chemical properties
>Information on basic physicochemical properties
- Appearance liquid
- OdourNo data available
- Odour ThresholdNo data available
- pH7 (20g/l, H2O, 20℃)
- Melting point/freezing pointMelting point/range: -93 °C - lit.
- Initial boiling point and boiling range 72 - 73 °C - lit.
- Flash point-7 °C
- Evaporation rateNo data available
- Flammability (solid, gas)No data available
- Upper/lower flammability or explosive limits2.6-13.4%(V)
- Vapour pressure88 mm Hg ( 20 °C)
- Vapour density3 (vs air)
- Relative density0,934 g/cm3 at 25 °C
- Water solubility20g/l
- Partition coefficient: n-octanol/waterNo data available
- Autoignition temperatureNo data available
- Decomposition temperatureNo data available
- ViscosityNo data available
- Explosive propertiesNo data available
- Oxidizing propertiesNo data available
- Henry's Law Constant4.81 (calculated, Howard, 1989)
>Other safety information
No data available
SECTION 10: Stability and reactivity
>Reactivity
No data available
>Chemical stability
Stable under recommended storage conditions.
>Possibility of hazardous reactions
Unstable upon depletion of inhibitor.
>Conditions to avoid
Heat, flames and sparks.
>Incompatible materials
>Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available
In the event of fire: see section 5
SECTION 11: Toxicological information
>Information on toxicological effects
Acute toxicity
Remarks: (RTECS) Inhalation: absorption
LD50 Dermal - Rabbit - 2.335 mg/kg Remarks: (RTECS)
Skin corrosion/irritation
Result: No skin irritation - 4 h (OECD Test Guideline 404)
Drying-out effect resulting in rough and chapped skin. Possible damages: slight irritation
Serious eye damage/eye irritation
Result: No eye irritation (OECD Test Guideline 405)
Possible damages: slight irritation
Respiratory or skin sensitisation
Germ cell mutagenicity
Escherichia coli/Salmonella typhimurium Result: negative
Mutagenicity (mammal cell test): chromosome aberration. Human lymphocytes
Result: positive Micronucleus test
human lymphoblastoid cells Result: negative
In vitro mammalian cell gene mutation test human lymphoblastoid cells
Result: positive
Mouse - male - sperm Result: negative (ECHA)
OECD Test Guideline 474 Mouse - male - Bone marrow
Result: Positive results were obtained in some in vivo tests.
Carcinogenicity
IARC: 2B - Group 2B: Possibly carcinogenic to humans (Vinyl acetate)
Reproductive toxicity
Specific target organ toxicity - single exposure
Acute oral toxicity - Gastrointestinal disturbance, Risk of aspiration upon vomiting., Pulmonary failure possible after aspiration of vomit.
Acute inhalation toxicity - mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Specific target organ toxicity - repeated exposure
Aspiration hazard
Additional Information
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
After uptake:
Systemic effects:
Dizziness, somnolence, Unconsciousness Absorption can result in damage to:
Liver, Kidney
Effect potentiated by: ethanol
This substance should be handled with particular care.
Toxicity
SECTION 12: Ecological information
>Toxicity
static test EC50 - Daphnia magna (Water flea) - 12,6 mg/l - 48 h (OECD Test Guideline 202)
>Persistence and degradability
Biodegradability aerobic - Exposure time 14 d
Result: 82 - 98 % - Readily biodegradable. (OECD Test Guideline 301C)
>Bioaccumulative potential
No data available
>Mobility in soil
>Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
>Toxics Screening Level
>Other adverse effects
Harmful to aquatic life.
Discharge into the environment must be avoided.
SECTION 13: Disposal considerations
>Waste treatment methods
> Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material
must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
Incompatibilities
Vinyl acetate may undergo spontaneous exothermic polymerization on exposure to light. Vapors may form explosive mixture with air. Incompatible with oxidizers; contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, strong light and UV. The vapor may react vigorously with silica gel or aluminum, acids, bases, silica gel, etc.
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
> Contaminated packaging
Dispose of as unused product.
SECTION 14: Transport information
>UN number
ADR/RID: 1301 IMDG: 1301 IATA: 1301
>UN proper shipping name
| | ADR/RID: VINYL ACETATE, STABILIZED IMDG: VINYL ACETATE, STABILIZED | |
| IATA: Vinyl acetate, stabilized | ||
| 14.3 | Transport hazard class(es) ADR/RID: 3 IMDG: 3 | IATA: 3 |
| 14.4 | Packaging group ADR/RID: II IMDG: II | IATA: II |
| 14.5 | Environmental hazards ADR/RID: no IMDG Marine pollutant: no | IATA: no |
> 14.6 Special precautions for user
No data available
SECTION 15: Regulatory information
>Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulations on the Safety Management of Hazardous Chemicals
Measures for Environmental Management of New Chemical Substances
SECTION 16: Other information
>Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
>References
【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/
【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/
>Other Information
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