甲基环己烷 · 英文 MSDS

CAS：108-87-2

Safety Data Sheet

Product name: MethylcyclohexaneCAS No.: 108-87-2

Prepared in accordance with GB/T 16483, GB/T 17519

SECTION 1: Identification of the substance/mixture and of the company/undertaking

>Product identifier

Product name: Methylcyclohexane
CBnumber: CB7852767
CAS: 108-87-2
EINECS Number: 203-624-3
Synonyms: methylcyclohexane,Sextone B

>Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

>Company Identification

Company: Linyi Tuohui New Materials Co., Ltd.
Address: Room A6159, 6F, Building 1, Linyi Software Park, No.6 Yihe Road, Zhimadun Subdistrict, Yishui New Area, Linyi City, Shandong Province, China
Telephone: +86 176 6460 5089 (Manager Niu) / +86 130 4664 1786 (Manager Li)
Email: nathan@tuohui-chem.com
WhatsApp: +86 176 6460 5089
Emergency telephone: +86 176 6460 5089

SECTION 2: Hazards identification

>GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordDanger

Precautionary statements

P501 Dispose of contents/container to.....

P405 Store locked up.

P403+P235 Store in a well-ventilated place. Keep cool.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403 Store in a well-ventilated place.

P391 Collect spillage. Hazardous to the aquatic environment

P370+P378 In case of fire: Use ... for extinction.

P331 Do NOT induce vomiting.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P273 Avoid release to the environment.

P271 Use only outdoors or in a well-ventilated area.

P270 Do not eat, drink or smoke when using this product.

P264 Wash skin thoroughly after handling.

P264 Wash hands thoroughly after handling.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P243 Take precautionary measures against static discharge.

P240 Ground/bond container and receiving equipment.

P233 Keep container tightly closed.

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Hazard statements

H412 Harmful to aquatic life with long lasting effects

H411 Toxic to aquatic life with long lasting effects

H410 Very toxic to aquatic life with long lasting effects

H401 Toxic to aquatic life

H336 May cause drowsiness or dizziness

H320 Causes eye irritation

H315 Causes skin irritation

H304 May be fatal if swallowed and enters airways

H302 Harmful if swallowed

H225 Highly Flammable liquid and vapour

SECTION 3: Composition/information on ingredients

>Substance

Product name: Methylcyclohexane
Synonyms: methylcyclohexane,Sextone B
CAS: 108-87-2
EC number: 203-624-3
MF: C7H14
MW: 98.19

SECTION 4: First aid measures

>Description of first aid measures

General advice

Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air. Call in physician.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

In case of eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

If swallowed

After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Call a physician immediately.

>Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

>Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

>Extinguishing media

Suitable extinguishing media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

>Special hazards arising from the substance or mixture

Carbon oxides Combustible.

Pay attention to flashback.

Vapors are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

>Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

>Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.

>NFPA 704

SECTION 6: Accidental release measures

>Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.

>Environmental precautions

Do not let product enter drains. Risk of explosion.

>Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.

Chemizorb). Dispose of properly. Clean up affected area.

>Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

>Precautions for safe handling

> Advice on safe handling

Avoid generation of vapours/aerosols.

> Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

> Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

>Conditions for safe storage, including any incompatibilities

> Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and

sources of ignition.

>Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

>control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

>Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate

government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,4 mm Break through time: 480 min

Material tested:Camatril (KCL 730 / Aldrich Z677442, Size M)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 30 min

Material tested:KCL 741 Dermatril L

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection

Recommended Filter type: Filter A-(P2)

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains. Risk of explosion.

Exposure limits

NIOSH REL: TWA 400 ppm (1,600 mg/m³), IDLH 1,200 ppm; OSHA PEL: TWA 500 ppm (2,000 mg/m³); ACGIH TLV: TWA 400 ppm (adopted).

SECTION 9: Physical and chemical properties

>Information on basic physicochemical properties

Appearancecolorless liquid
Odouraromatic
Odour Threshold0.15ppm
pHNo data available
Melting point/freezing pointMelting point/range: -126 °C - lit.
Initial boiling point and boiling range101 °C - lit.
Flash point-4 °C - closed cup
Evaporation rateNo data available
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limits Upper explosion limit: 6,7 %(V) Lower explosion limit: 1,1 %(V)
Vapour pressure 61,8 hPa at 25 °C
Vapour density 3,4
Relative densityNo data available
Water solubility0,014 g/l at 25 °C
Partition coefficient: n-octanol/waterlog Pow: 3,6 at 25 °C - Bioaccumulation is not expected., (Lit.)
Autoignition temperatureNo data available
Decomposition temperatureNo data available
ViscosityViscosity, kinematic: No data available Viscosity, dynamic: 0,679 mPa.s at 20 °C
Explosive propertiesNo data available
Oxidizing propertiesNo data available
Henry's Law Constant0.0678 at 25.0 °C (Ramachandran et al., 1996)
λmaxλ: 207 nm Amax: 1.00
λ: 221 nm Amax: 0.40
λ: 232 nm Amax: 0.15
λ: 260 nm Amax: 0.05
λ: 300-400 nm Amax: 0.01

>Other safety information

Surface tension 23,29 mN/m at 25 °C

Relative vapor density

3,4

SECTION 10: Stability and reactivity

>Reactivity

Vapors may form explosive mixture with air.

>Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

>Possibility of hazardous reactions

Risk of explosion with:

Oxygen

Exothermic reaction with:

Oxidizing agents

fire-promoting substances

>Conditions to avoid

Warming.

>Incompatible materials

various plastics

>Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

>Information on toxicological effects

Acute toxicity

LC50 Inhalation - Rat - male - 4 h - > 52,6 mg/l
LD50 Dermal - Rabbit - > 86.000 mg/kg Remarks: (Lit.)

Skin corrosion/irritation

Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product.

Serious eye damage/eye irritation

Eyes - Rabbit
Result: No eye irritation (OECD Test Guideline 405)
Remarks: The value is given in analogy to the following substances: Cyclohexane Possible damages: slight irritation

Respiratory or skin sensitization

Buehler Test - Guinea pig
Result: Does not cause skin sensitization. (OECD Test Guideline 406)
Remarks:
The value is given in analogy to the following substances: Cyclohexane

Germ cell mutagenicity

Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471
Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration. Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative

Carcinogenicity

No data available

Reproductive toxicity

Specific target organ toxicity - single exposure

May cause drowsiness or dizziness. - Central nervous system

Specific target organ toxicity - repeated exposure Aspiration hazard

Aspiration hazard, Aspiration may cause pulmonary edema and pneumonitis.

Toxicity

Acute oral LD₅₀ for mice 2,250 mg/kg (quoted, RTECS, 1985).

SECTION 12: Ecological information

>Toxicity

Toxicity to fish

semi-static test LC50 - Oryzias latipes (Orange-red killifish) - 2,07 mg/l - 96 h

(OECD Test Guideline 203)

Toxicity to daphnia and other aquatic invertebrates

semi-static test EC50 - Daphnia magna (Water flea) - 0,326 mg/l - 48 h

(OECD Test Guideline 202)

Toxicity to algae

static test ErC50 - Pseudokirchneriella subcapitata (algae) - 0,134 mg/l - 72 h

(OECD Test Guideline 201)

static test NOEC - Pseudokirchneriella subcapitata (algae) - 0,0221 mg/l - 72 h

(OECD Test Guideline 201)

Toxicity to bacteria

static test NOEC - activated sludge - 2,755 mg/l - 14 d Remarks: (ECHA)

>Persistence and degradability

Biodegradability aerobic - Exposure time 28 d

Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301D)

>Bioaccumulative potential

>Mobility in soil

>Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

>Toxics Screening Level

The ITSL for methylcyclohexane is 16,000 μg/m3 based on an 8-hour averaging time.

>Other adverse effects

No data available

SECTION 13: Disposal considerations

>Waste treatment methods

> Product

See www.retrologistik.com for processes regarding the return of chemicals and

containers, or contact us there if you have further questions.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some plastics, rubber and coatings

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

SECTION 14: Transport information

>UN number

ADR/RID: 2296 IMDG: 2296 IATA: 2296

>UN proper shipping name

	ADR/RID: METHYLCYCLOHEXANE IMDG: METHYLCYCLOHEXANE
IATA: Methylcyclohexane
14.3	Transport hazard class(es) ADR/RID: 3 IMDG: 3	IATA: 3
14.4	Packaging group ADR/RID: II IMDG: II	IATA: II
14.5	Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes	IATA: no
14.6	Special precautions for user No data available

SECTION 15: Regulatory information

>Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

EC Inventory:Listed.

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

SECTION 16: Other information

>Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

>References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

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