片碱（氢氧化钠） · 英文 MSDS

CAS：1310-73-2

Safety Data Sheet

Product name: Sodium hydroxideCAS No.: 1310-73-2

Prepared in accordance with GB/T 16483, GB/T 17519

SECTION 1: Identification of the substance/mixture and of the company/undertaking

>Product identifier

Product name: Sodium hydroxide
CBnumber: CB8105015
CAS: 1310-73-2
EINECS Number: 215-185-5
Synonyms: NaOH,sodium hydroxide

>Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

>Company Identification

Company: Linyi Tuohui New Materials Co., Ltd.
Address: Room A6159, 6F, Building 1, Linyi Software Park, No.6 Yihe Road, Zhimadun Subdistrict, Yishui New Area, Linyi City, Shandong Province, China
Telephone: +86 176 6460 5089 (Manager Niu) / +86 130 4664 1786 (Manager Li)
Email: nathan@tuohui-chem.com
WhatsApp: +86 176 6460 5089
Emergency telephone: +86 176 6460 5089

SECTION 2: Hazards identification

>GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordDanger

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P405 Store locked up.

Hazard statements

H290 May be corrosive to metals

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

SECTION 3: Composition/information on ingredients

>Substance

Product name: Sodium hydroxide
Synonyms: NaOH,sodium hydroxide
CAS: 1310-73-2
EC number: 215-185-5
MF: NaOH
MW: 39.9971

SECTION 4: First aid measures

>Description of first aid measures

General advice

First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air. Call in physician.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

In case of eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

>Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

>Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

>Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

>Special hazards arising from the substance or mixture

Sodium oxides Not combustible.

Ambient fire may liberate hazardous vapours.

>Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

>Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

>NFPA 704

SECTION 6: Accidental release measures

>Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

>Environmental precautions

Do not let product enter drains.

>Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.

>Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

>Precautions for safe handling

For precautions see section 2.2.

>Conditions for safe storage, including any incompatibilities

> Storage conditions

No metal containers.

Tightly closed. Dry.

>Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

>control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

>Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate

government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:KCL 741 Dermatril L

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:KCL 741 Dermatril L

Body Protection

protective clothing

Respiratory protection

required when dusts are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Recommended Filter type: Filter type P2

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

Exposure limits

TLV-TWA air 2 mg/m³ (OSHA); ceiling 2 mg/m³ (ACGIH) and 2 mg/m³/15 min (NIOSH).

SECTION 9: Physical and chemical properties

>Information on basic physicochemical properties

Appearancewhite pellets
Odourodorless
Odour ThresholdNot applicable
pHca.>14 at 100 g/l at 20 °C
Melting point/freezing pointMelting point/range: 318 °C
Initial boiling point and boiling range1.390 °C at 1.013 hPa
Flash pointNot applicable
Evaporation rateNo data available
Flammability (solid, gas)The product is not flammable.
Upper/lower flammability or explosive limitsNo data available
Vapour pressure< 24 hPa at 20 °C
Vapour density 1,38 - (Air = 1.0)
Relative density2.13
Water solubility1.090 g/l at 20 °C
Partition coefficient: n-octanol/waterNot applicable for inorganic substances
Autoignition temperatureNo data available
Decomposition temperature176-178 ºC
ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
Explosive propertiesNo data available
Oxidizing propertiesNo data available
λmaxλ: 260 nm Amax: 0.015
λ: 280 nm Amax: 0.01

>Other safety information

Relative vapor 1,38 - (Air = 1.0)

density

SECTION 10: Stability and reactivity

>Reactivity

No data available

>Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

>Possibility of hazardous reactions

Violent reactions possible with:

Acetone Chlorine Ethylene oxide Fluorine

Hydrogen halides Hydrazine hydrate hydroxylamine Acid anhydrides Acrolein

Acid chlorides Acids

sulfuric acid Chloroform Water

hydrogen peroxide anhydrides phosphides

halogen-halogen compounds trichloroethene

can decompose violently in contact with:

Organic Substances hydrogen sulphide

Risk of ignition or formation of inflammable gases or vapours with: powdered aluminium

Ammonium salts persulfates

Sodium borohydride phosphorus

Oxides of phosphorus Halogenated hydrocarbon Light metals

Metals

Risk of explosion/exothermic reaction with: Bromine

Calcium

in powder form furfuryl alcohol Nitromethane Peroxides

organic nitro compounds Nitriles

Acrylic monomers Chloroform

with Acetone

Nitrobenzene with Methanol Nitrobenzene with

salts magnesium Zinc

and Tin

(in the presence of atmospheric oxygen and/or moisture)

>Conditions to avoid

no information available

>Incompatible materials

Aluminum, brass, Metals, metal alloys, Zinc, Tin

>Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

>Information on toxicological effects

Acute toxicity

Oral
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach.
Symptoms: burns of mucous membranes, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Dermal

Skin corrosion/irritation

Skin - Rabbit
Result: Causes burns.
Remarks: (Regulation (EC) No 1272/2008, Annex VI)

Serious eye damage/eye irritation

Eyes - Rabbit
Result: Causes serious eye damage. (OECD Test Guideline 405)
Remarks: (Regulation (EC) No 1272/2008, Annex VI) Causes serious eye damage.

Respiratory or skin sensitization

Patch test: - In vitro study Result: negative Remarks: (ECHA)

Germ cell mutagenicity

No data available

Carcinogenicity

Reproductive toxicity

Specific target organ toxicity - single exposure

Specific target organ toxicity - repeated exposure

Aspiration hazard

Toxicity

LD orally in rabbits: 500 mg/kg (10% soln) (Fazekas)

SECTION 12: Ecological information

>Toxicity

Toxicity to fish

LC50 - Gambusia affinis (Mosquito fish) - 125 mg/l - 96 h Remarks: (ECOTOX Database)

Toxicity to daphnia and other aquatic invertebrates

EC50 - Ceriodaphnia (water flea) - 40,4 mg/l - 48 h Remarks: (ECHA)

Toxicity to bacteria

EC50 - Photobacterium phosphoreum - 22 mg/l - 15 min Remarks: (External MSDS)

>Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

>Bioaccumulative potential

No data available

>Mobility in soil

>Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

>Toxics Screening Level

The Initial Threshold Screening Level (ITSL) for sodium hydroxide is 8 μg/m3 with a 1-hour averaging time. The previous ITSL established on 9/14/1992 was 20 μg/m3 (1-hour averaging time).

>Other adverse effects

Harmful effect due to pH shift.

Forms corrosive mixtures with water even if diluted.

Neutralisation possible in waste water treatment plants. Discharge into the environment must be avoided.

SECTION 13: Disposal considerations

>Waste treatment methods

Incompatibilities

A strong base and a strong oxidizer. Violent reaction with acid. Incompatible with water; flammable liquids; organic halogens, nitromethane, and nitrocompounds, combustibles. Contact with moisture or water may generate heat. Corrosive to metals. Contact with zinc, aluminum, tin and lead in the presence of moisture, forming explosive hydrogen gas. Attacks some forms of plastics, rubber or coatings.

> Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Waste Disposal

Discharge into tank containing water, neutralize, then flush to sewer with water.

SECTION 14: Transport information

>UN number

ADR/RID: 1823 IMDG: 1823 IATA: 1823

>UN proper shipping name

	ADR/RID: SODIUM HYDROXIDE, SOLID IMDG: SODIUM HYDROXIDE, SOLID
IATA: Sodium hydroxide, solid
14.3	Transport hazard class(es) ADR/RID: 8 IMDG: 8	IATA: 8
14.4	Packaging group ADR/RID: II IMDG: II	IATA: II
14.5	Environmental hazards ADR/RID: no IMDG Marine pollutant: no	IATA: no
14.6	Special precautions for user No data available

SECTION 15: Regulatory information

>Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

EC Inventory:Listed.

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

SECTION 16: Other information

>Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

>References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

>Other Information

The occupational exposure limit value should not be exceeded during any part of the working exposure.NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.Other UN number: UN1824 Sodium hydroxide solution, Hazard class 8, packing group II-III.

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